新疆艾比湖流域枯、丰水期三维荧光光谱特性及其与水质的关系     

王迪  张飞  张兆永  张海威  朱世丹  张贤龙 《湖泊科学》2020,32(2):483-495

以艾比湖流域主要入湖河流为研究对象，在5月（丰水期）和8月（枯水期）分别沿博尔塔拉河（博河）和精河进行采样，采用平行因子模型（PARAFAC）和三维荧光区域积分法对水体三维荧光特性进行研究并对其与水质的关系在枯、丰水期下的变化进行探讨.结果表明①河流DOM在枯水期与丰水期都含有C1（240、425 nm） UVC类腐殖质，C2（225、290 nm）紫外区内络氨酸类有机物，C3（230/280、330 nm）蛋白类有机物，C4（265、260 nm）腐殖质类共4种组分.通过对水体三维荧光进行区域积分可以看出DOM荧光成分的占比在不同时期的变化.博河在枯水期时EEM光谱中的区域Ⅲ富里酸含量低于丰水期，枯水期时区域Ⅱ芳香类蛋白质、区域Ⅳ可溶性微生物代谢物以及区域Ⅴ类腐殖质酸高于丰水期；对于精河来说，区域Ⅱ芳香类蛋白质和区域Ⅳ可溶性微生物代谢物在枯水期的含量高于丰水期，区域Ⅲ富里酸和区域Ⅴ类腐殖质酸的含量枯水期低于丰水期，这表明水体腐质化程度较高.②本研究选取了一些常规的荧光指数来描述枯、丰水期水体的荧光指数特性.经研究发现，精河的荧光指数、自生源指数和腐殖化指数在不同时期的变化幅度较小，而博河的变化幅度较大.③将荧光指数与水质参数进行相关性分析并建模，结果表明枯水期自生源指数（BIX）与化学需氧量呈显著正相关，相关系数R=0.688；丰水期时BIX与铵态氮浓度呈显著负相关，相关系数R=-0.493.通过对比分析艾比湖主要入湖河流的三维荧光光谱特性与水质在枯、丰水期时的关系进一步表明水体中DOM的特性以及在枯、丰水期下的差异，为艾比湖流域的治理改善提供一定的理论支持和参考依据.  相似文献   

Impacts of confining pressure and safety thickness on water and mud inrush in weathered granite     

Jinquan Liu  Weizhong Chen  Zhiping Deng  Taogen Liu 《Marine Georesources & Geotechnology》2020,38(2):144-153

Abstract

Due to the strong disintegration and water erosion of completely weathered granite, water and mud inrush disasters are apt to take place in this zone during underwater tunnel construction. The pore, compactness, seepage path length, fracture geometries and their interconnections for water and mud transfer are strongly influenced by confining pressure and waterproof-resistant slab safety thickness. In order to inspect the influence, a series of experiments based on a self-designed testing system and non-Darcy testing method were performed. The results indicated that the water and mud inrush evolution increased with the increase of confining pressure and decreased with the increase of safety thickness. In particular, the confining pressure mainly influences the initial evolution stage, and a critical safety thickness to prevent water and mud inrush is obtained. Besides, the non-Darcy testing method results shows that the water and mud inrush evolution affects the influence of non-Darcy flow. For example, while the safety thickness was smaller than the critical value, the evolution was large and unstable and its behavior transferred into nonlinear. In this case, the flow changed to non-Darcy flow.  相似文献   

地震后水汽异常变化初探     

王勇  任栋  娄泽生  郝振航 《大地测量与地球动力学》2019,39(9):881-883

研究东日本地震、汶川地震和玉树地震震中及其附近区域在地震前后的水汽时间序列变化。首先分析震中MODIS水汽序列和震中附近探空站点水汽序列在地震前后的变化；然后基于GNSS ZTD与水汽之间的高相关性，以GNSS ZTD代替GNSS水汽，讨论震源区周围IGS站点的ZTD序列变化。研究发现，震后震中及其附近区域水汽值变化出现异常，且距离越近所受影响越大；水汽不断聚积，达到峰值后发生降水。  相似文献   

Faecal indicator bacteria in New Zealand freshwater fish: a pilot study     

Sarah Coxon  Jon S Harding  Brent Gilpin 《新西兰海洋与淡水研究杂志》2019,53(3):470-479

Recent studies have suggested that poikilothermic animals, such as fish, may represent a previously overlooked source of the faecal indicator bacteria (FIB) used for the assessment of water quality. However, quantitative studies of FIB in poikilotherms are scarce. We investigated the presence of FIB in the faeces of five freshwater fish species. E. coli and enterococci were detected in 71 and 76% of faecal samples, respectively. Concentrations were highly variable, with maximum concentrations (2.1?×?10⁴ E. coli and 1.3?×?10⁶ enterococci per gram of faecal material) up to four orders of magnitude higher than present in the water column. FIB were not detected in faecal samples from marine fish. Our findings suggest that FIB ingested from the environment may be capable of replication within the fish gut, making fish a potential source and transport mechanism for FIB in New Zealand freshwaters. This may have implications for water quality monitoring.  相似文献   

Inter- and intra-annual trend analysis of water level and flow in the middle and lower reaches of the Ganjiang River,China     

Di Zhu  Yue Ben  Xinfa Xu 《水文科学杂志》2020,65(12):2128-2141

ABSTRACT

The Ganjiang River is the largest tributary of Poyang Lake in China, and its hydrological regime variation greatly affects the utilization of regional water resources and the ecological environment of the lake. In this study, a novel trend analysis method, the Moving Average over Shifting Horizon (MASH), was applied to investigate the inter- and intra-annual trends of flow and water level from 1976 to 2016 at the Xiajiang and the Waizhou hydrological stations in the Ganjiang River. The Significant Change Rate Method (SCRM) was proposed to determine the MASH averaging parameters. The trend analysis results show a statistically significant decrease in water level series throughout the year and the relationship of flow and water level have changed greatly at the Waizhou station. The sediment load reduction, large-scale sand mining and water level decrease of Poyang Lake are identified as the main causes for the water level decrease.  相似文献   

Investigating potential future changes in surface water flooding hazard and impact     

Alison C. Rudd  Alison L. Kay  Steven C. Wells  Timothy Aldridge  Steven J. Cole  Elizabeth J. Kendon  Elizabeth J. Stewart 《水文研究》2020,34(1):139-149

Surface water flooding (SWF) is a recurrent hazard that affects lives and livelihoods. Climate change is projected to change the frequency of extreme rainfall events that can lead to SWF. Increasingly, data from Regional Climate Models (RCMs) are being used to investigate the potential water-related impacts of climate change; such assessments often focus on broad-scale fluvial flooding and the use of coarse resolution (>12 km) RCMs. However, high-resolution (<4 km) convection-permitting RCMs are now becoming available that allow impact assessments of more localised SWF to be made. At the same time, there has been an increasing demand for more robust and timely real-time forecast and alert information on SWF. In the UK, a real-time SWF Hazard Impact Model framework has been developed. The system uses 1-km gridded surface runoff estimates from a hydrological model to simulate the SWF hazard. These are linked to detailed inundation model outputs through an Impact Library to assess impacts on property, people, transport, and infrastructure for four severity levels. Here, a set of high-resolution (1.5 km and 12 km) RCM data has been used as input to a grid-based hydrological model over southern Britain to simulate Current (1996–2009) and Future (~2100s; RCP8.5) surface runoff. Counts of threshold-exceedance for surface runoff and precipitation (at 1-, 3- and 6-hr durations) are analysed. Results show that the percentage increases in surface runoff extremes, are less than those of precipitation extremes. The higher-resolution RCM simulates the largest percentage increases, which occur in winter, and the winter exceedance counts are greater than summer exceedance counts. For property impacts, the largest percentage increases are also in winter; however, it is the 12-km RCM output that leads to the largest percentage increase in impacts. The added-value of high-resolution climate model data for hydrological modelling is from capturing the more intense convective storms in surface runoff estimates.  相似文献   

Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

Characterizing hydrological processes within kettle holes using stable water isotopes in the Uckermark of northern Brandenburg,Germany     

Stuart Andrew Vyse  Majid Taie Semiromi  Gunnar Lischeid  Christoph Merz 《水文研究》2020,34(8):1868-1887

Understanding the hydrologic connectivity between kettle holes and shallow groundwater, particularly in reaction to the highly variable local meteorological conditions, is of paramount importance for tracing water in a hydro(geo)logically complex landscape and thus for integrated water resource management. This article is aimed at identifying the dominant hydrological processes affecting the kettle holes' water balance and their interactions with the shallow groundwater domain in the Uckermark region, located in the north-east of Germany. For this reason, based on the stable isotopes of oxygen (δ¹⁸O ) and hydrogen (δ²H ), an isotopic mass balance model was employed to compute the evaporative loss of water from the kettle holes from February to August 2017. Results demonstrated that shallow groundwater inflow may play the pivotal role in the processes taking part in the hydrology of the kettle holes in the Uckermark region. Based on the calculated evaporation/inflow (E/I) ratios, most of the kettle holes (86.7%) were ascertained to have a partially open, flow-through-dominated system. Moreover, we identified an inverse correlation between E/I ratios and the altitudes of the kettle holes. The same holds for electrical conductivity (EC) and the altitudes of the kettle holes. In accordance with the findings obtained from this study, a conceptual model explaining the interaction between the shallow groundwater and the kettle holes of Uckermark was developed. The model exhibited that across the highest altitudes, the recharge kettle holes are dominant, where a lower ratio of E/I and a lower EC was detected. By contrast, the lowest topographical depressions represent the discharge kettle holes, where a higher ratio of E/I and EC could be identified. The kettle holes existing in between were categorized as flow-through kettle holes through which the recharge takes place from one side and discharge from the other side.  相似文献   

Bound and mobile soil water isotope ratios are affected by soil texture and mineralogy,whereas extraction method influences their measurement     

Rachel E. Adams  Ayumi Hyodo  Toby SantaMaria  Cynthia L. Wright  Thomas W. Boutton  Jason B. West 《水文研究》2020,34(4):991-1003

Questions persist about interpreting isotope ratios of bound and mobile soil water pools, particularly relative to clay content and extraction conditions. Interactions between pools and resulting extracted water isotope composition are presumably related to soil texture, yet few studies have manipulated the bound pool to understand its influence on soil water processes. Using a series of drying and spiking experiments, we effectively labelled bound and mobile water pools in soils with varying clay content. Soils were first vacuum dried to remove residual water, which was then replaced with heavy isotope-enriched water prior to oven drying and spiking with heavy isotope-depleted water. Water was extracted via centrifugation or cryogenic vacuum distillation (at four temperatures) and analysed for oxygen and hydrogen isotope ratios via isotope ratio mass spectrometry. Water from centrifuged samples fell along a mixing line between the two added waters but was more enriched in heavy isotopes than the depleted label, demonstrating that despite oven drying, a residual pool remains and mixes with the mobile water. Soils with higher clay + silt content appeared to have a larger bound pool. Water from vacuum distillation samples have a significant temperature effect, with high temperature extractions yielding progressively more heavy isotope-enriched values, suggesting that Rayleigh fractionation occurred at low temperatures in the vacuum line. By distinctly labelling bound and mobile soil water pools, we detected interactions between the two that were dependent on soil texture. Although neither extraction method appeared to completely extract the combined bound and mobile (total water) pool, centrifugation and high temperature cryogenic vacuum distillations were comparable for both δ²H and δ¹⁸O of soil water isotope ratios.  相似文献   

Shenandoah Watershed Study-Virginia Trout Stream Sensitivity Study (SWAS-VTSSS): Stream water quality and hydrologic monitoring data for mid-Appalachian headwater streams     

Ami L. Riscassi  Todd M. Scanlon  Suzanne W. Maben  James N. Galloway 《水文研究》2021,35(4):e14164

The Shenandoah Watershed Study (established in 1979) and the Virginia Trout Stream Sensitivity Study (established in 1987) serve to increase understanding of hydrological and biogeochemical changes in western Virginia mountain streams that occur in response to acidic deposition and other ecosystem stressors. The SWAS-VTSSS program has evolved over its 40+ year history to consist of a temporally robust and spatially stratified monitoring framework. Currently stream water is sampled for water quality bi-hourly during high-flow events at three sites and weekly at four sites within Shenandoah National Park (SHEN), and quarterly at 72 sites and on an approximately decadal frequency at ~450 sites within the wider western Virginia Appalachian region. Stream water is evaluated for pH, acid neutralizing capacity (ANC), base cations (calcium, magnesium, sodium and potassium ion), acid anions (sulphate, nitrate and chloride), silica, ammonium, and conductivity with a subset of samples evaluated for monomeric aluminium and dissolved organic carbon. Hourly stream discharge (four sites) and in-situ measurements of conductivity, water and air temperature (three sites) are also measured within SHEN. Here we provide an overview and timeline of the SWAS-VTSSS stream water monitoring program, summarize the field and laboratory methods, describe the water chemistry and hydrologic data sets, and document major watershed disturbances that have occurred during the program history. Website links and instructions are provided to access the stream chemistry and time-series monitoring data in open-access federal databases. The purpose of this publication is to promote awareness of these unique, long-term data sets for wider use in catchment studies. The water chemistry and hydrologic data can be used to investigate a wide range of biogeochemical research questions and provide key inputs for models of these headwater stream ecosystems. SWAS-VTSSS is an ongoing program and quality assured data sets are uploaded to the databases annually.  相似文献